Publications & Journals

10/16/2024 |

Humidity-Induced Degradation Mapping of Pt3Co ORR Catalyst for PEFC by In-Operando Electrochemistry and Ex Situ SAXS

Joel Mata Edjokola, Marco Bogar, Maximillian Grandi, Rodolfo Taccani, Heinz Amenitsch, Marjan Marinšek, Viktor Hacker and Merit Bodner

This study investigates the degradation mechanisms of Pt3Co catalysts under varying humidity conditions using accelerated stress testing. Pt3Co experiences a 77% performance loss, significant structural changes, and increased resistance, while Pt shows a 30% loss. Electrochemical impedance spectroscopy and small-angle X-ray scattering reveal Pt3Co’s high sensitivity to humidity gradients, highlighting its vulnerability to dealloying and accelerated performance decay.

Small, 2024

Link to Article